NEET UG · Chemistry · Chapter 18

The d and f Block Elements NEET PYQs (1988–2026)

115 questions from The d and f Block Elements have appeared in NEET UG between 1988 and 2026, including 25 in the last five papers (2022–2026). The most-asked topic is Properties of D-Block Elements (43 questions). Practise them all with instant answers and step-by-step solutions.

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Questions
115
Years covered
36
Topics
7
Difficulty
E 54 · M 57 · H 4

Solved The d and f Block Elements PYQs

3 recent questions with answers. The full set of 115 is free to practise.

  1. NEET 2026MediumOxidation States
    Q1
    The green paramagnetic species formed by heating KMnO4 at 513 K is:
    • AK2MnO4
    • BMn3O4
    • CMnO
    • DKO2
    Show answer & solution

    Correct answer: (A)

    2KMnO4 → K2MnO4 + MnO2 + O2. K2MnO4 is green and paramagnetic (Mn in +6 oxidation state, d1).
  2. NEET 2026HardMagnetic Properties
    Q2
    The lanthanide ion having four unpaired electrons is (Given: Atomic numbers of Ce = 58, Nd = 60, Tb = 65 and Ho = 67):
    • ANd³+
    • BCe³+
    • CTb³+
    • DHo³+
    Show answer & solution

    Correct answer: (D)

    Ce³+: [Xe]4f1 (1 unpaired)

    Nd³+: [Xe]4f³ (3 unpaired)

    Tb³+: [Xe]4f8 (8 unpaired? Actually 4f8 has 8 electrons, unpaired = 8?

    No, for 4f, maximum unpaired is 7 in half-filled. So 4f8 has 6 unpaired?

    Let me calculate: For f orbital, maximum 14 electrons, half-filled 7.

    4f8 has 6 unpaired (since 8 > 7, so 7 paired? Actually 4f8: 6 unpaired?

    No, 4f8 has 6 unpaired and 2 paired. So 6 unpaired.)

    Ho³+: [Xe]4f10 (10 electrons, 4 unpaired? Since 14-10=4, so 4

    unpaired.)

    So Ho³+ has 4 unpaired electrons.
  3. NEET 2026HardProperties of D-Block Elements
    Q3
    Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.

    Assertion A: Generally, 3d transition metals have high melting points.

    Reason R: Involvement of 3d-electrons in addition to 4s-electrons in the interatomic metallic bonding.

    In light of the above statements, choose the most appropriate answer from the options given below:
    • ABoth A and R are correct and R is the correct

      explanation of A
    • BBoth A and R are correct and R is NOT the correct

      explanation of A
    • CA is correct but R is not correct
    • DA is not correct but R is correct
    Show answer & solution

    Correct answer: (A)

    3d transition metals have high melting points due to involvement of both3d and 4s electrons in metallic bonding. So A and R are correct and R is the correct explanation.
Practise all 115 The d and f Block Elements PYQs

Topic-wise question count

Where NEET has asked from The d and f Block Elements, most frequent first.

  • Properties of D-Block Elements43
  • Magnetic Properties19
  • Applications and Reactions19
  • Oxidation States13
  • Isomerism in Coordination Compounds13
  • Crystal Field Theory (CFT)7
  • Coordination Number and Oxidation State1

Year-wise The d and f Block Elements questions in NEET

Number of questions from this chapter in each year's paper(s).

2026
5
2025
2
2024
9
2023
4
2022
5
2021
3
2019
4
2018
2
2017
3
2016
3
2015
5
2014
3
2013
4
2012
6
2011
2
2010
5
2009
1
2008
1
2007
2
2006
3
2005
3
2004
2
2003
2
2002
5
2001
2
2000
1
1999
4
1998
4
1997
4
1996
4
1995
2
1994
2
1993
1
1991
1
1989
4
1988
2

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